Product ID:SODIUM SULFIDE, SEE SUPPLEMENTAL
MSDS Date:03/23/1998
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKTTH

Emergency Phone: 800-227-1150

Info Phone: 800-227-1150

Cage: 59896

Telephone: 800-227-1150/910-584-0381

Cage: 59896

SODIUM SULFIDE

CAS: 1313-84-4

RTECS: WE1925000

LD50 LC50 Mixture:IPR-MUS LD50:53MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:DANGER!MAY BE FATAL IF SWALLOWED OR
INHALED.CORROSIVE,CAUSES BURNS.CONTACT WITH ACID LIBERATES
POISONOUS GAS.TARGET ORGANS: HEART AND RESPIRATORY CONDITIONS.
EYES: MAY CAUSE IRRITATION. SKIN: MAY CAUS E IRRITATION. INGESTION:
MAY CAUSE GASTROINTESTINAL DISCOMFORT. INHALATION: MAY CAUSE
IRRITATION TO RESPIRATORY TRACT.
Explanation of Carcinogenicity:CHRONIC: MATERIAL IS NOT LISTED AS
CAUSING CANCER AGENT.
Effects of Overexposure:NAUSEA, VOMITING, DIARRHEA, HEADACHE, DIZZINESS
AND HEART PALPITATIONS BY INGESTION. NASAL CONGESTION, COUGH,
SHORTNESS OF BREATHE AND RAPID BREATHING BY INHALATION.
Medical Cond Aggravated by Exposure:SEVERE IRRITATION OR BURNS TO EYES,
SKIN & RESPIRATORY TRACT

First Aid:EYES-FLUSH WITH WATER FOR AT LEAST 15 MINUTES, RAISING AND
LOWERING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IF IRRITATION
PERSISTS. SKIN-THOROUGHLY WASH EXPOSED AREA FOR AT LEAST 15
MINUTES. REMOV E CONTAMINATED CLOTHING. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION
PERSISTS. INGESTION: IF SWALLOWED, IF CONSCIOUS, GIVE PLENTY OF
WATER AND INDUCE VOMITING IMMED IATELY AS DIRECTED BY MEDICAL
PERSONNEL. IMMEDIATELY CALL A PHYSICIAN OR POISON CONTROL CENTER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION:
REMOVE TO FRESH AIR. GIVE OXYGEN IF B REATHING IS DIFFICULT; (SEE
OTHER INFO)

Extinguishing Media:USE DRY CHEMICAL, CO2 OR APPROPRIATE FOAM.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE
EQUIPMENT AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:EMITS FLAMMABLE AND TOXIC HYDROGEN
SULFIDE GAS.

Spill Release Procedures:VENTILATE AREA OF SPILL. CLEAN-UP PERSONNEL
SHOULD WEAR PROPER PROTECTIVE EQUIPMENT. AVOID CREATING DUST. SWEEP
OR SCOOP UP AND CONTAINERIZE FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:MUST REFRIGERATE. STORE AWAY FROM
ACIDS AND OXIDIZERS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:NONE NEEDED UNDER NORMAL CONDITIONS OF USE WITH
ADEQUATE VENTILATION. NIOSH APPROVED EQUIPMENT SHOULD BE WORN IF
PELS ARE EXCEEDED.
Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION:YES.
SPECIAL AND OTHER :NO.
Protective Gloves:RUBBER, NEOPRENE, PVC, OR EQUIVALENT.
Eye Protection:SPLASH PROOF CHEMICAL SAFETY GOGGLES SHOULD BE WORN AT
ALL TIMES.
Other Protective Equipment:LAB COAT, EYE WASH, AND SAFETY SHOWER.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
PRODUCT CODES:89-1770, 89-1772.

HCC:B1
Boiling Pt:=920.C, 1688.F
B.P. Text:DECMPOSES
Melt/Freeze Pt:=50.C, 122.F
Decomp Temp:=920.C, 1688.F
Spec Gravity:1.43@16C
Solubility in Water:SOLUBLE

Stability Indicator/Materials to Avoid:YES
REACT WITH ACID TO FORM HYDROGEN SULFIDE GAS. CORRODES CONTAINERS MADE
OF MOST METALS.
Stability Condition to Avoid:ACIDS, OXIDIZERS.
Hazardous Decomposition Products:H2S, SOX
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE, AND LOCAL REGULATIONS. ALWAYS CONTACT A PERMITTED
WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE. EPA WASTE NUMBER: D003.

Toxicological Information:IPR-MUS LD50:53MG/KG. CHRONIC:MATERIAL IS NOT
LISTED AS CAUSING CANCER AGENT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:EPA WASTE NUMBER:D003.

Transport Information:PER MSDS:TRANSPORT INFORMATION DESCRIPTION:SODIUM
SULFIDE, HYDRATED, 8, UN1849, II.

SARA Title III Information:SARA SEC 311/312 REPORTING:ACUTE. SARA EHS
SEC 302 TPQ:NO. SARA SEC 313:NO.
Federal Regulatory Information:CERCLA SEC 103 RQ LBS:NO. RCRA SEC
261.33:NO.